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Sample 3: TJC Prelim 2000 Q4 / GCE (S) Nov 99 Q4
The relation between current I and temperature T in a certain device is
I = AT2e-B/T
where A and B are constants. Fig. 4.1 shows values of I and T obtained experimentally.
I/A | 1.6x10-5 | 1.7x10-6 | 1.5x10-7 | 1.9x10-9 | 1.6x10-10 |
T/K | 740 | 700 | 660 | 600 | 570 |
(a) The value of B may be obtained from a linear graph of suitable functions of I and T. State the graph to be plotted and explain how the value of B is deduced from it.
(b) Obtain values of the required functions of I ant T. Plot the graph. Deduce the value of B from your graph.
Thinking Process:
Part (a)
Step 1:
First, recognise that there is an exponential function in the equation, hence you need to loge both sides.
Step 2:
However, if you loge both sides directly, you are going to end up with an equation involving logeI, logeT and B/T, which is not a linear graph, as required by the question.
Step 3:
Hence, before loge both sides, divide throughout by T2 so the equation becomes:
I/T2 = Ae-B/T
Step 4:
Now you can loge both sides, to obtain:
loge(I/T2) = logeA - B/T
Step 5:
Plotting loge(I/T2) against 1/T gives a linear graph with gradient -B and y-intercept logeA
Part (b)
Step 1:
Re-tabulate the table adding three more rows for 1/T, I/T2 and loge(I/T2), as follows:
I/A | 1.6x10-5 | 1.7x10-6 | 1.5x10-7 | 1.9x10-9 | 1.6x10-10 |
T/K | 740 | 700 | 660 | 600 | 570 |
1/T | 1.35x10-3 | 1.43x10-3 | 1.52x10-3 | 1.67x10-3 | 1.75x10-3 |
I/T2 | 2.9x10-11 | 3.5x10-12 | 3.4x10-13 | 5.3x10-15 | 4.9x10-16 |
loge(I/T2) | -24.3 | -26.4 | -28.7 | -32.9 | -35.2 |
Step 2:
Plot loge (I/T2) against 1/T, as shown in the graph below:
Step 3:
From the graph, find the gradient, which is -27250. Thus -B = -27250. The value of B is 27250.
If need be, you can also find the value of logeA, which is 12.5.
This gives the value of A as 2.68 x 103.
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