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Sample 3:  TJC Prelim 2000 Q4 / GCE (S) Nov 99 Q4

The relation between current I and temperature T in a certain device is

I = AT2e-B/T

where A and B are constants. Fig. 4.1 shows values of I and T obtained experimentally.

I/A 1.6x10-5 1.7x10-6 1.5x10-7 1.9x10-9 1.6x10-10
T/K 740 700 660 600 570

(a) The value of B may be obtained from a linear graph of suitable functions of I and T. State the graph to be plotted and explain how the value of B is deduced from it.

(b) Obtain values of the required functions of I ant T. Plot the graph. Deduce the value of B from your graph.

Thinking Process:

Part (a)

Step 1: 

First, recognise that there is an exponential function in the equation, hence you need to loge both sides.

Step 2:

However, if you loge both sides directly, you are going to end up with an equation involving logeI, logeT and B/T, which is not a linear graph, as required by the question.

Step 3:

Hence, before loge both sides, divide throughout by T2 so the equation becomes:

I/T2 = Ae-B/T

Step 4:

Now you can loge both sides, to obtain:

loge(I/T2) = logeA - B/T

Step 5:

Plotting loge(I/T2) against 1/T gives a linear graph with gradient -B and y-intercept logeA

Part (b)

Step 1: 

Re-tabulate the table adding three more rows for 1/T, I/T2 and loge(I/T2), as follows:

I/A 1.6x10-5 1.7x10-6 1.5x10-7 1.9x10-9 1.6x10-10
T/K 740 700 660 600 570
1/T 1.35x10-3 1.43x10-3 1.52x10-3 1.67x10-3 1.75x10-3
 I/T2 2.9x10-11 3.5x10-12 3.4x10-13 5.3x10-15 4.9x10-16
 loge(I/T2) -24.3 -26.4 -28.7 -32.9 -35.2

Step 2:

Plot loge (I/T2) against 1/T, as shown in the graph below:

 

Step 3:

From the graph, find the gradient, which is -27250. Thus -B = -27250. The value of B is 27250.

If need be, you can also find the value of logeA, which is 12.5.

This gives the value of A as 2.68 x 103.

 

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